Product ID:WHITMIRE PT 270
MSDS Date:09/11/1991
FSC:6840
NIIN:01-338-2487
MSDS Number: BJZRC

WHITMIRE RESEARCH LABORATORIES INC.

3568 TREE COURT INDUSTRIAL BLVD.
ST. LOUIS, MO 63122
US

Emergency Phone: 314-576-0120/800-424-9300(CHEMTREC)

Info Phone: 314-225-5371/800-777-8570

Preparer: MICHAEL G. SARLI

Cage: 67184

WHITMIRE MICRO GEN RESEARCH LABORATORIES, INC.

ST LOUIS, MO 63122-6620 US

Telephone: 636-225-5371

Cage: 67184

CHLORPYRIFOS (SARA III)

CAS: 2921-88-2

RTECS: TF6300000

Fraction By Weight: 0.5%

OSHA PEL S, 0.2 MG/M3

ACGIH TLV: S, 0.2 MG/M3; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 95%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 4.5%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:LD50(ORAL RAT) IS 82MG/KG (CHLORPYRIFOS)
Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY PRODUCE EYE IRRITATION. PROLONGED
EXPOSURE MAY CAUSE SKIN IRRITATION. EXCESSIVE EXPOSURE MAY PRODUCE
SIGNS OF CHOLINESTERASE DEPRESSION. INGESTION AND INHALATION ARE
UNLIKELY DUE TO THE PRODUCT BE ING A PRESSURIZED PRODUCT AND
PRODUCINGPARTICLES LARGE ENOUGH NOT TO BE RESPIRABLE.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:SIGNS OF CHOLINESTERASE DEPRESSION: DISCOMFORT
OR TIGHTNESS IN CHEST, DIFFICULTY IN BREATHING, STOMACH PAINS,
NAUSEA, VOMITING, DIARRHEA, CRAMPS, HEADACHE, NERVOUSNESS,
WEAKNESS, NONACTIVE PINPOINT PU PILS OR BLURRED VISION. SYMPTOMS
MAY NOTOCCUR UNTIL 1-8 HOURS AFTER EXPOSURE.
Medical Cond Aggravated by Exposure:NONE KNOWN

First Aid:IF SWALLOWED: CALL A PHYSICIAN IMMEDIATELY. GASTRIC LAVAGE IS
INDICATED. VOMITING MAY CAUSE ASPIRATION PNEUMONIA. IF INHALED:
REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF POISONING SYMPTOMS
OCCUR. IF ON SKIN: WASH AFFECTED AREA WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. IF IRRITATION PERSISTS, CALL A PHYSICIAN. IF
IN EYES: FLUSH EYES WITH PLENTY OF WATER. GET IMMEDIATE MEDICAL
ATTENTION.

Extinguishing Media:CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE. EXPOSURE TO
TEMPERATURES ABOVE 130F MAY CAUSE BURSTING.

Spill Release Procedures:IF CONTAINER BEGINS TO LEAK, ALLOW TO
DISCHARGE COMPLETELY IN WELL VENTILATED AREA. THEN, DISPOSE IN SAFE
PLACE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE. DO NOT STORE NEAR HEAT OR
OPEN FLAME. TEMPERATURES >130F MAY CAUSE BURSTING.
Other Precautions:WASH THOROUGHLY AFTER USING. AVOID CONTAMINATION OF
FOOD, UTENSILS AND FOOD PREPARATION AREAS.

Respiratory Protection:NONE REQUIRED IF USED ACCORDING TO LABEL
DIRECTIONS. AVOID BREATHING SPRAY MIST. IF EXPOSURE GUIDELINES ARE
EXCEEDED, USE AN APPROVED AIR PURIFYING RESPIRATOR.
Ventilation:PROVIDE ADEQUATE VENTILATION OF TREATMENT AREA
Protective Gloves:NONE REQUIRED - AVOID SKIN CONTACT.
Eye Protection:SAFETY GLASSES OR GOGGLES ARE RECOMMEND.
Other Protective Equipment:NONE
Work Hygienic Practices:WASH THOROUGHLY AFTER USING. AVOID
CONTAMINATION OF FOOD, UTENSILS, AND FOOD PREPARATION AREAS.
Supplemental Safety and Health
NONE

HCC:V2
Vapor Pres:AEROSOL
Spec Gravity:1.3
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SPRAYS AS A STRONG MIST WITH CHARACTERISTIC DURSBAN
Percent Volatiles by Volume:99.5

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:DO NOT SPRAY INTO OPEN FLAME OR ONTO VERY
HOT SURFACES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION IN OPEN FLAME
WILL RESULT IN HALOGEN ACIDS AND CARBON DIOXIDE.

Waste Disposal Methods:AEROSOL CYLINDER IS NOT REFILLABLE. DO NOT
ATTEMPT TO RECHARGE. WHEN CYLINDER IS EXHAUSTED, DISCARD IN SAFE
PLACE. DO NOT THROW IN FIRE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.